Partial oxidation of methane to syngas in tubular oxygen-permeable reactor

被引：8
|
作者：
Wang, HH [1 ]
Cong, Y [1 ]
Yang, WS [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
来源：
CHINESE SCIENCE BULLETIN | 2002年 / 47卷 / 07期
关键词：
membrane reactor; oxygen separation; POM; mixed-conducting membrane; syngas; perovskite;
D O I：
10.1360/02tb9123
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
A dense Ba0.5Sr0.5Co0.8Fe0.2O3-delta membrane tube was prepared by the extruding method. Furthermore, a membrane reactor with this tubular membrane was successfully applied to partial oxidation of methane (POM) reaction, in which the separation of oxygen from air and the partial oxidation of methane are integrated in one process. At 875degreesC, 94% of methane conversion, 98% of CO selectivity, 95% of H-2 selectivity, and as high as 8.8 mL/(min (.) cm(2)) of oxygen flux were obtained. In POM reaction condition. the membrane tube shows a very good stability.
引用
收藏
页码：534 / 537
页数：4
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