Nickel Phosphide Corrosion Induced by Water and Corrosion Inhibition

被引：1
|
作者：
Yang Bo [1 ,2 ,3 ]
Lu Cong-Xuan [1 ]
Zhang Xu-Qiang [1 ]
Ma Jian-Tai [3 ]
机构：
[1] Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 38卷 / 07期
关键词：
transition metal phosphide; corrosion; metal oxide protective layer; stability; NASCENT FORMED OXYGEN; HYDROGEN-EVOLUTION; HIGH-PERFORMANCE; VISIBLE-LIGHT; CATALYSTS; ELECTROCATALYST; PHOTOCORROSION; SHELL; CDS; COP;
D O I：
10.11862/CJIC.2022.106
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Transition metal phosphides as cocatalysts have been widely used in electrocatalysis, photoelectrocataly. sis, and electrochemical energy storage. But its stability in water medium is seldom studied. Nickel phosphide ( NixP) was synthesized and the reaction of NixP with H2O was studied in detail. The results showed that serious corrosion of NixP occurred when NixP was dispersed in the water while H-2 was generated. At the same time, the corrosion products of PO43- and Ni2+ ions were detected. Such NixP corrosion in water is highly dependent on NixP crystal struc. ture and components. The deposition of NiO, ZnO, and TiO2 metal oxide protective layer on NixP can improve the anti. corrosion ability of NixP in the aqueous medium.
引用
收藏
页码：1337 / 1349
页数：13
相关论文
共 46 条
  • [11] Nickel phosphide: the effect of phosphorus content on hydrogen evolution activity and corrosion resistance in acidic medium
    Kucernak, Anthony R. J.
    Sundaram, Venkata N. Naranammalpuram
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (41) : 17435 - 17445
  • [12] ELECTROLYTIC OXYGEN EVOLUTION ON NI-CO-P ALLOYS
    KUPKA, J
    BUDNIOK, A
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1990, 20 (06) : 1015 - 1020
  • [13] Nanocrystalline Ni5P4: a hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic media
    Laursen, A. B.
    Patraju, K. R.
    Whitaker, M. J.
    Retuerto, M.
    Sarkar, T.
    Yao, N.
    Ramanujachary, K. V.
    Greenblatt, M.
    Dismukes, G. C.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (03) : 1027 - 1034
  • [14] The Synthesis of Nanostructured Ni5P4 Films and their Use as a Non-Noble Bifunctional Electrocatalyst for Full Water Splitting
    Ledendecker, Marc
    Calderon, Sandra Krick
    Papp, Christian
    Steinrueck, Hans-Peter
    Antonietti, Markus
    Shalom, Menny
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (42) : 12361 - 12365
  • [15] Stabilization of n-cadmium telluride photoanodes for water oxidation to O2(g) in aqueous alkaline electrolytes using amorphous TiO2 films formed by atomic-layer deposition
    Lichterman, Michael F.
    Carim, Azhar I.
    McDowell, Matthew T.
    Hu, Shu
    Gray, Harry B.
    Brunschwig, Bruce S.
    Lewis, Nathan S.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (10) : 3334 - 3337
  • [16] Catalysts for hydrogen evolution from the [NiFe] hydrogenase to the Ni2P(001) surface:: The importance of ensemble effect
    Liu, P
    Rodriguez, JA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (42) : 14871 - 14878
  • [17] Improvement of hydrodeoxygenation stability of nickel phosphide based catalysts by silica modification as structural promoter
    Liu, Xuguang
    Li, Zhenyu
    Zhang, Baoquan
    Hu, Maocong
    [J]. FUEL, 2017, 204 : 144 - 151
  • [18] Synthetic Levers Enabling Independent Control of Phase, Size, and Morphology in Nickel Phosphide Nanoparticles
    Muthuswamy, Elayaraja
    Savithra, Galbokka H. Layan
    Brock, Stephanie L.
    [J]. ACS NANO, 2011, 5 (03) : 2402 - 2411
  • [19] Inhibition of CdS photocorrosion by Al2O3 shell for highly stable photocatalytic overall water splitting under visible light irradiation
    Ning, Xiaofeng
    Zhen, Wenlong
    Wu, Yuqi
    Lu, Gongxuan
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 226 : 373 - 383
  • [20] Inhibition of photocorrosion of CdS via assembling with thin film TiO2 and removing formed oxygen by artificial gill for visible light overall water splitting
    Ning, Xiaofeng
    Li, Jian
    Yang, Baojun
    Zhen, Wenlong
    Li, Zhen
    Tian, Bin
    Lu, Gongxuan
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 212 : 129 - 139
12345