Crystal structure and magnetic properties of the spin crossover complex FeII(ethyl nicotinate)2[AuI(CN)2]2

被引：23

作者：

Sugaya, Akihiro ^{[1
]}

Ueno, Shotaro ^{[1
]}

Okabayashi, Jun ^{[2
]}

Kitazawa, Takafumi ^{[1
,3
]}

机构：

[1] Toho Univ, Fac Sci, Dept Chem, Chiba 2748510, Japan

[2] Univ Tokyo, Res Ctr Spectrochem, Bunkyo Ku, Tokyo 1130033, Japan

[3] Toho Univ, Res Ctr Mat Integrated Properties, Chiba 2748510, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 05期

关键词：

CADMIUM CYANIDE HOST; TRANSITION; FRAMEWORK; PRESSURE; BEHAVIOR; COMPOUND; STATE; 2D; CONVERSION; MECHANISM;

D O I：

10.1039/c3nj01564e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new Fe-II two-step spin crossover (SCO) coordination polymer, Fe-II(ethyl nicotinate)(2)[Au-I(CN)(2)](2) 1, with four-inflection associated with phase transitions, has been synthesized. Complex 1 with large side chain ligands has been found to undergo unbalanced two-step SCO transitions. This phenomenon is associated with aurophilic interactions through the pairing of bilayers and quadruple effects.

引用

页码：1955 / 1958

页数：4

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