A Unique Cascade Reaction between 3-Arylprop-2-inylcarboxylates and Benzaldehydes Leading to the Formation of Morita-Baylis-Hillman Adducts

被引：15
|
作者：
Karpaviciene, Ieva [1 ]
Cikotiene, Inga [1 ]
机构：
[1] Vilnius State Univ, Fac Chem, Dept Organ Chem, LT-03225 Vilnius, Lithuania
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 01期
关键词：
PHENYL VINYL KETONE; ALDEHYDES; ACRYLATE; THIOACRYLATE; DIMERIZATION; CATALYSIS; ALKYNES; BF3;
D O I：
10.1021/ol303319a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
During an alkyne-carbonyl metathesis reaction between electron-rich 3-arylprop-2-inylcarboxylates and electron-poor benzaldehydes, a smooth migration of carboxylate groups takes place. This unique cascade reaction allows the formation of Morita-Baylis-Hillman (MBH) adducts unavailable via a traditional MBH reaction.
引用
收藏
页码：224 / 227
页数：4
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