Pulsed laser-assisted ionic liquid electrodeposition of gallium nanoparticles and germanium nanostructures for energy storage

被引:25
|
作者
Yu, Zhaoliang [1 ,2 ]
Meng, Xiangdong [1 ,2 ]
Yin, Mo [2 ]
Sun, Meng [2 ]
Yuan, Meng [2 ]
Li, Haibo [2 ]
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
[2] Jilin Normal Univ, Minist Educ, Key Lab Funct Mat Phys & Chem, Siping 136000, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Semiconductor; Nanostructure; Pulsed laser; Ionic liquid; Electrodeposition; SIZE CONTROL; ABLATION; GE; PERFORMANCE; ANODES;
D O I
10.1016/j.cplett.2018.03.023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ga nanoparticles and Ge nanostructures have been electrodeposited from 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm]Tf2N) ionic liquid with pulsed laser assistance. Laser irradiation led to clustering and vertical growth of Ga nanospheres, and formation of Ge nanowires and branched nanowires. Ge nanowires were also electrodeposited on a Cu foil under laser irradiation. The as-prepared Ge nanowires film anode yielded an initial discharge and charge capacity of 1646 mAh/g and 1278 mAh/g, respectively, and retained nearly 70% of the original charge capacity after 50 cycles at 0.2 C. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:181 / 186
页数:6
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