Effects of nano-materials on 17O NMR line-width of water clusters

被引:8
|
作者
Yan, Ying [1 ]
Ou, Xiao-xia [1 ]
Zhang, Hui-ping [1 ]
Shao, Yan [2 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China
[2] Wuyi Univ, Sch Chem & Environm Engn, Jianginen 529020, Guangdong, Peoples R China
关键词
Nano-materials; Water clusters; O-17 NMR line-width; HYDROGEN-BONDS; SPECTRA; SCATTERING; (H2O)(N);
D O I
10.1016/j.molstruc.2013.08.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Effects of nano-materials on O-17 NMR line-width of water clusters have been measured. Different water samples were prepared by adding nano-materials into distilled water and tap water. The average particle size and distribution of nano-materials were characterized, meanwhile, the ions, pH values, total dissolved solids (TDS) and O-17 NMR line-width of different water samples were also tested. The effects of time and temperature on O-17 NMR line-width of water sample prepared by adding nano-materials into tap water (pH = 8.3) were analyzed as well. The experimental results showed that the particle size distribution of the nano-materials is from 1 to 300 nm, the average particle size is 95.5 nm and the median particle size is 44.7 nm. The nano-materials were mainly composed of calcium. After adding moderate nano-materials into different water samples, the O-17 NMR line-width of distilled water decreased from 59 Hz to 44 Hz and the tap water decreased from 113 Hz to 53 Hz. The O-17 NMR line-width of water sample prepared by adding a certain amount of nano-materials into tap water (pH = 83) is almost the same after 42 days, and the value keeps nearly unchanged as the temperature increases from 30 degrees C to 85 degrees C. (C) 2013 Published by Elsevier B.V.
引用
收藏
页码:211 / 214
页数:4
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