Initial heats of H2S adsorption on activated carbons:: Effect of surface features

被引：22

作者：

Bagreev, A

Adib, F

Bandosz, TJ ^{[1
]}

机构：

[1] CUNY City Coll, Grad Sch, Dept Chem, New York, NY 10021 USA

[2] CUNY City Coll, Ctr Water Resources & Environm Res, New York, NY 10031 USA

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1999年 / 219卷 / 02期

关键词：

activated carbons; inverse gas chromatography; hydrogen sulfide; porosity; heat of adsorption;

D O I：

10.1006/jcis.1999.6485

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The sorption of hydrogen sulfide was studied on activated carbons of various origins by means of inverse gas chromatography at infinite dilution. The conditions of the experiment were dry and anaerobic. Prior to the experiments the surface of some carbon samples was oxidized using either nitric acid or ammonium persulfate. Then the structural parameters of carbons were evaluated from the sorption of nitrogen. From the IGC experiments at various temperatures, heats of adsorption were calculated. The results showed that the heat of H2S adsorption under dry anaerobic conditions does not depend on surface chemistry. The dependence of the heat of adsorption on the characteristic energy of nitrogen adsorption calculated from the Dubinin-Raduskevich equation was found. This correlation can be used to predict the heat of H2S adsorption based on the results obtained from nitrogen adsorption. (C) 1999 Academic Press.

引用

页码：327 / 332

页数：6

共 50 条

[41] Influence of Loading a Tertiary Amine on Activated Carbons and Effect of CO2 on Adsorptive H2S Removal from Biogas
Quan, Wenying
Jiang, Xiao
Wang, Xiaoxing
Song, Chunshan
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (27): : 9998 - 10008
[42] Effect of activated carbons modification on porosity, surface structure and phenol adsorption
Stavropoulos, G. G.
Samaras, P.
Sakellaropoulos, G. P.
JOURNAL OF HAZARDOUS MATERIALS, 2008, 151 (2-3) : 414 - 421
[43] H2S and HS- adsorption on a charged Cu surface in an electrolyte:: Effect of ionic strength
Wilson, WD
Schaldach, CM
MICROSCOPIC SIMULATION OF INTERFACIAL PHENOMENA IN SOLIDS AND LIQUIDS, 1998, 492 : 207 - 212
[44] A computational study of adsorption of H2S and SO2 on the activated carbon surfaces
Hussain, Akhtar
JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 2023, 122
[45] Combined effect of adsorption and biodegradation of H2S with FPU immobilization
Key Laboratory of Urban Human Residential Environmental Science and Technology, Shenzhen Graduate School, Peking University, Shenzhen 518055, China
不详
Yingyong Jichu yu Gongcheng Kexue Xuebao, 2007, 3 (308-316):
[46] First principles calculation of adsorption for H2S on Fe(100) surface
Luo Qiang
Tang Bin
Zhang Zhi
Ran Zeng-Ling
ACTA PHYSICA SINICA, 2013, 62 (07)
[47] Oxidation of H2S on activated carbon KAU and influence of the surface state
Brazhnyk, Dmitrii V.
Zaitsev, Yuri P.
Bacherikova, Irina V.
Zazhigalov, Valery A.
Stoch, Jerzy
Kowal, Andrzey
APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 70 (1-4) : 557 - 566
[48] Ab initio simulation of H2S adsorption on the (100) surface of pyrite
Stirling, A
Bernasconi, M
Parrinello, M
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (09): : 4934 - 4939
[49] DFT study on the adsorption and dissociation of H2S on CuO(111) surface
Sun, Shujuan
Zhang, Dongsheng
Li, Chunyu
Wang, Yanji
RSC ADVANCES, 2015, 5 (28): : 21806 - 21811
[50] The adsorption and dissociation of H2S on Cu(100) surface: A DTF study
Chen, Shenghui
Sun, Shuangqing
Lian, Bingjie
Ma, Yunfei
Yan, Youguo
Hu, Songqing
SURFACE SCIENCE, 2014, 620 : 51 - 58

← 1 2 3 4 5 →