First palladium-catalyzed aminations of aryl chlorides

被引：100
|
作者：
Beller, M
Riermeier, TH
Reisinger, CP
Herrmann, WA
机构：
[1] Anorganisch-chemisches Institut, TU München
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 12期
关键词：
D O I：
10.1016/S0040-4039(97)00289-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium-catalyzed coupling reaction of aryl chlorides with various amines has been studied for the first rime. Crucial for the success of this C-N bond forming reaction is the use of potassium tertbutoxide as base. Turn over numbers up to 900 and yields up to 80 % have been obtained. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：2073 / 2074
页数：2
相关论文
共 50 条
  • [41] Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Tosylates with Hydrazine
    Lundgren, Rylan J.
    Stradiotto, Mark
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (46) : 8686 - 8690
  • [42] MECHANISM OF PALLADIUM-CATALYZED TRANSFER HYDROGENOLYSIS OF ARYL CHLORIDES BY FORMATE SALTS
    RAJAGOPAL, S
    SPATOLA, AF
    JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (05): : 1347 - 1355
  • [43] Palladium-catalyzed arylation of electron-rich heterocycles with aryl chlorides
    Chiong, Hendrich A.
    Daugulis, Olafs
    ORGANIC LETTERS, 2007, 9 (08) : 1449 - 1451
  • [44] Palladium-catalyzed synthesis of N-aryloxazolidinones from aryl chlorides
    Ghosh, A
    Sieser, JE
    Riou, M
    Cai, WL
    Rivera-Ruiz, L
    ORGANIC LETTERS, 2003, 5 (13) : 2207 - 2210
  • [45] Palladium-catalyzed cross-coupling reaction of silicone with aryl chlorides
    Koike, T
    Mori, A
    SYNLETT, 2003, (12) : 1850 - 1852
  • [46] A General, Practical Palladium-Catalyzed Cyanation of (Hetero)Aryl Chlorides and Bromides
    Senecal, Todd D.
    Shu, Wei
    Buchwald, Stephen L.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (38) : 10035 - 10039
  • [47] Palladium-catalyzed C-H bond arylation with aryl chlorides
    Chiong, Hendrich A.
    Daugulis, Olafs
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [48] Mild and general methods for the palladium-catalyzed cyanation of aryl and heteroaryl chlorides
    Littke, Adam
    Soumeillant, Maxime
    Kaltenbach, Robert F., III
    Cherney, Robert J.
    Tarby, Christine M.
    Kiau, Susanne
    ORGANIC LETTERS, 2007, 9 (09) : 1711 - 1714
  • [49] An Improved Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides
    Pan, Jun
    Wang, Xinyan
    Zhang, Yong
    Buchwald, Stephen L.
    ORGANIC LETTERS, 2011, 13 (18) : 4974 - 4976
  • [50] Efficient palladium-catalyzed coupling reactions of aryl bromides and chlorides with phenols
    Hu, Tongjie
    Schulz, Thomas
    Torborg, Christian
    Chen, Xiaorong
    Wang, Jun
    Beller, Matthias
    Huang, Jun
    CHEMICAL COMMUNICATIONS, 2009, (47) : 7330 - 7332
12345