Synthesis, characterization and electrochemical properties of cyanide-bridged cobalt(III) iron(II) complexes

被引：0

作者：

Zhan, SZ ^{[1
]}

Chen, XY ^{[1
]}

Meng, QJ ^{[1
]}

Xei, W ^{[1
]}

机构：

[1] HENAN NORMAL UNIV,DEPT CHEM,XINXIANG 453002,PEOPLES R CHINA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1996年 / 26卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five new cyanide-bridged cobalt(III)/iron(II) complexes have been synthesized. The complexes were characterized by elemental analyses, spectral analyses and electrochemical techniques. The presence of cyanide bridges is evident from the IR and UV-vis spectra by the shift of nu((C=N)) and changes in lambda(max) with respect to the mononuclear parent complex Fe(phen)(2)(CN)(2) (phen is I,10-phenanthroline). The cyclic voltammogram of cyano-bridged cobalt(III)/iron(II) complexes indicates that they all exhibit two pairs of reversible peaks.

引用

页码：277 / 284

页数：8

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