Preparation and Characterization of Alcogels Based on (Poly Ethylene Glycol Methyl Ether Methacrylate-Acrylic Acid) Copolymers

被引：6

作者：

Najafi, Vahid ^{[1
]}

Kabiri, Kourush ^{[1
]}

Ziaee, Farshid ^{[1
]}

机构：

[1] IPPI, Tehran, Iran

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2013年 / 52卷 / 07期

关键词：

Acrylic acid; Alcogel; Alcohol absorbency; Polyethylene glycol methyl ether methacrylate; POLY(ETHYLENE GLYCOL); POLY(ACRYLIC ACID); POLYMERIZATION; ORGANOGELS; HYDROGELS;

D O I：

10.1080/03602559.2012.762664

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Alcohol absorbents based on poly ethylene glycol methyl ether methacrylate (PEGMEMA) macromer and acrylic acid (AA) were prepared via solution polymerization using trimethyl propane triacrylate (TMPTA) as crosslinker. Swelling capacity of gels was measured in water, ethanol and methanol. Alcohol absorbency was increased with increasing AA content, which can be related to the ability of an AA segment in formation of H-bonding and dissociation of COOH groups to produce of mobile ions. The alcogels absorb ethanol and methanol up to 14.8 and 17.4g/g, respectively. TG analysis shows that increasing AA content caused an increase of thermal stability of alcogels.

引用

页码：667 / 673

页数：7

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