Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds

被引：91
|
作者：
Wu, Zheng-Jian
Li, Shi-Rui
Long, Hao
Xu, Hai-Chao [1 ]
机构：
[1] Xiamen Univ, Innovat Collaborat Ctr Chem Energy Mat, Key Lab Chem Biol Fujian Prov, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 36期
基金：
中国国家自然科学基金;
关键词：
C-H; METAL-FREE; MANGANESE(III) ACETATE; RADICAL REACTIONS; TETRACYCLIC CORE; OXINDOLES; CATALYSIS; REAGENT; FUNCTIONALIZATION; GENERATION;
D O I：
10.1039/c8cc02472c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The intramolecular C(sp(3))-H/C(sp(2))-H cross-coupling of 1,3-dicarbonyl compounds has been achieved through Cp2Fe-catalyzed electrochemical oxidation. The key to the success of these dehydrogenative cyclization reactions is the selective activation of the acidic -C-H bond of the 1,3-dicarbonyl moiety to generate a carbon-centered radical.
引用
收藏
页码：4601 / 4604
页数：4
相关论文
共 50 条
  • [41] The direct fluorination of 1,3-dicarbonyl and related compounds.
    Hutchinson, J
    Chambers, RD
    Greenhall, MP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 12 - FLUO
  • [42] REACTIONS OF 2-BENZOYLACETAMIDINE WITH 1,3-DICARBONYL COMPOUNDS
    SOLLHUBERKRETZER, M
    TROSCHUTZ, R
    ARCHIV DER PHARMAZIE, 1982, 315 (09) : 783 - 790
  • [43] OXIDATIVE ADDITION OF 1,3-DICARBONYL COMPOUNDS TO CONJUGATED OLEFINS
    VINOGRADOV, MG
    KONDORSKY, AE
    NIKISHIN, GI
    SYNTHESIS-STUTTGART, 1988, (01): : 60 - 62
  • [44] Enantio- and diastereoselective diarylmethylation of 1,3-dicarbonyl compounds
    Li, Xin
    He, Songtao
    Song, Qiuling
    CHEMICAL SCIENCE, 2020, 11 (23) : 5969 - 5973
  • [45] Fluorocontaining 1,3-dicarbonyl compounds in the synthesis of pyrimidine derivatives
    Burgart, YV
    Kuzueva, OG
    Pryadeina, MV
    Kappe, CO
    Saloutin, VI
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 37 (06) : 869 - 880
  • [46] INDEPENDENT EFFECT OF SUBSTITUENTS ON ENOLIZABILITY OF 1,3-DICARBONYL COMPOUNDS
    KOLTSOV, AI
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1979, 28 (06): : 1278 - 1279
  • [47] Iminoiodane- and Bronsted Base-Mediated Cross Dehydrogenative Coupling of Cyclic Ethers with 1,3-Dicarbonyl Compounds
    Tejo, Ciputra
    Sim, Xiao Rong
    Lee, Bo Ra
    Ayers, Benjamin James
    Leung, Chung-Hang
    Ma, Dik-Lung
    Chan, Philip Wai Hong
    MOLECULES, 2015, 20 (07): : 13336 - 13353
  • [48] REACTION OF TRYPTOPHAN AND DERIVATIVES WITH SOME 1,3-DICARBONYL COMPOUNDS
    MACLAREN, JA
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1977, 30 (09) : 2045 - 2051
  • [49] Fluorocontaining 1,3-Dicarbonyl Compounds in the Synthesis of Pyrimidine Derivatives
    Ya.V. Burgart
    O.G. Kuzueva
    M.V. Pryadeina
    C.O. Kappe
    V.I. Saloutin
    Russian Journal of Organic Chemistry, 2001, 37 : 869 - 880
  • [50] Synthesis of Phosphonomethylated Bromoacetylfurans and Their Reactions with 1,3-Dicarbonyl Compounds
    Pevzner, L. M.
    Ponyaev, A. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (04) : 636 - 649
12345