Electrochemical dehydrogenative cyclization of 1,3-dicarbonyl compounds

被引：91
|
作者：
Wu, Zheng-Jian
Li, Shi-Rui
Long, Hao
Xu, Hai-Chao [1 ]
机构：
[1] Xiamen Univ, Innovat Collaborat Ctr Chem Energy Mat, Key Lab Chem Biol Fujian Prov, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 36期
基金：
中国国家自然科学基金;
关键词：
C-H; METAL-FREE; MANGANESE(III) ACETATE; RADICAL REACTIONS; TETRACYCLIC CORE; OXINDOLES; CATALYSIS; REAGENT; FUNCTIONALIZATION; GENERATION;
D O I：
10.1039/c8cc02472c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The intramolecular C(sp(3))-H/C(sp(2))-H cross-coupling of 1,3-dicarbonyl compounds has been achieved through Cp2Fe-catalyzed electrochemical oxidation. The key to the success of these dehydrogenative cyclization reactions is the selective activation of the acidic -C-H bond of the 1,3-dicarbonyl moiety to generate a carbon-centered radical.
引用
收藏
页码：4601 / 4604
页数：4
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