Regeneration of the iron-molybdenum catalyst for partial oxidation of methanol to formaldehyde

被引：1
|
作者：
Babichev, I. V. [1 ,2 ]
Ilyin, A. A. [2 ]
Rumyantsev, R. N. [2 ]
Ilyin, A. P. [2 ]
Kuryleva, K. V. [2 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo 153000, Russia
[2] Ivanovo State Univ Chem Technol, Res Inst Thermodynam & Kinet Chem Proc, Ivanovo 153000, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2015年 / 88卷 / 04期
关键词：
MOLYBDATE;
D O I：
10.1134/S1070427215040060
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Regeneration of a spent iron-molybdenum catalyst for partial oxidation of methanol to formaldehyde was studied. A stage-by-stage dissolution of molybdenum and iron oxides in solutions of ammonia and weak nitric acid, respectively, is suggested. A dependence of the catalyst composition on the pH of the medium and temperature and its effect on the catalyst properties in the reaction of methanol oxidation to formaldehyde was revealed.
引用
收藏
页码：590 / 594
页数：5
相关论文
共 50 条
  • [21] SELECTIVE OXIDATION OF METHANOL TO FORMALDEHYDE ON IRON VANADATE CATALYST
    Klissurski, Dimitar
    Abadzhieva, Nevena
    Kassabov, Stojan
    Stefanov, Plamen
    Kovacheva, Daniela
    Uzunov, Ivan
    COMPTES RENDUS DE L ACADEMIE BULGARE DES SCIENCES, 2009, 62 (09): : 1073 - 1078
  • [22] OXIDATION OF IRON-MOLYBDENUM AND NICKEL-MOLYBDENUM ALLOYS
    BRENNER, SS
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1955, 102 (01) : 7 - 15
  • [23] OXIDATION OF IRON-MOLYBDENUM AND NICKEL-MOLYBDENUM ALLOYS
    BRENNER, SS
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1955, 102 (09) : C219 - C219
  • [24] OXIDATION OF METHANOL TO FORMALDEHYDE OVER ANTIMONY-MOLYBDENUM OXIDE CATALYST
    MANN, RS
    DIAZREAL, RA
    STUDIES IN SURFACE SCIENCE AND CATALYSIS, 1993, 75 : 1991 - 1994
  • [25] Kinetics of the thermal treatment of an iron-molybdenum catalyst
    Kostynyuk, A. O.
    Gutenuar, F.
    Kalashnikova, A. N.
    Kalashnikov, Yu. V.
    Nikolenko, N. V.
    KINETICS AND CATALYSIS, 2014, 55 (05) : 649 - 655
  • [26] Kinetics of the thermal treatment of an iron-molybdenum catalyst
    A. O. Kostynyuk
    F. Gutenuar
    A. N. Kalashnikova
    Yu. V. Kalashnikov
    N. V. Nikolenko
    Kinetics and Catalysis, 2014, 55 : 649 - 655
  • [27] MoVW-mixed oxide as a partial oxidation catalyst for methanol to formaldehyde
    Ramachandra, B.
    Choi, Jung Sik
    Kim, Keun-Soo
    Choo, Ko-Yeon
    Sung, Jae-Suk
    Kim, Tae-Hwan
    NEW DEVELOPMENT AND APPLICATION IN CHEMICAL REACTION ENGINEERING, 4TH ASIA-PACIFIC CHEMICAL REACTION ENGINEERING SYMPOSIUM (APCRE 05), 2006, 159 : 273 - 276
  • [28] Surface structure and activity of iron molybdate catalyst for methanol oxidation to formaldehyde
    Zhang S.
    Zhang Y.
    Hu R.
    Zhen B.
    Han M.
    Han, Minghan (hanmh@tsinghua.edu.cn), 2016, Materials China (67): : 3678 - 3683
  • [29] IR-SPECTROSCOPIC STUDY OF THE NATURE OF THE SURFACE CENTERS AND ADSORPTION OF METHANOL BY IRON-MOLYBDENUM OXIDE CATALYST
    DAVYDOV, AA
    SHEPOTKO, ML
    TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA, 1990, 26 (04): : 474 - 480
  • [30] PREPARATION OF AN ACTIVE AND VERY SELECTIVE IRON MOLYBDENUM CATALYST FOR METHANOL OXIDATION
    IVANOV, K
    APPLIED CATALYSIS A-GENERAL, 1994, 116 (1-2) : L1 - L3
12345