Processing combustion synthesized Mg0.5Zr2(PO4)3 nanopowders to thin films as potential solid electrolytes

被引：6

作者：

Liu, Saiyue ^{[1
]}

Zhou, Chang ^{[1
]}

Wang, You ^{[1
]}

Yi, Eongyu ^{[2
]}

Wang, Weimin ^{[2
]}

Kieffer, John ^{[2
]}

Laine, Richard M. ^{[1
,2
]}

机构：

[1] Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Peoples R China

[2] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2020年 / 116卷

基金：

中国博士后科学基金;

关键词：

Powder processing; Nanocrystalline microstructure; Ceramics; Solid electrolytes; Mg0.5Zr2(PO4)(3); LI; BATTERIES; CONDUCTIVITY; SUBSTITUTION; MECHANISM; FRAMEWORK;

D O I：

10.1016/j.elecom.2020.106753

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Mg0.5Zr2(PO4)(3) is a promising electrolyte for Mg solid-state batteries. But it is difficult to achieve high-density thin films with phase purity. Here, we synthesized Mg-0.5(1+x)FexZr2-x(PO4)(3) nanopowders using liquid-feed flame spray pyrolysis and used the product to form transparent thin films via simple pressureless sintering at 1100 degrees C. The influence of Fe on the phase and microstructure were discussed and the bottlenecks during Mg2+ conduction pathway were calculated. The dense and high-purity Mg0.6Fe0.2Zr1.8(PO4)(3) exhibited an extremely low ionic area specific resistance of 1.6 k Omega cm(2) at 200 degrees C. This paper presents a method for preparing dense, high-purity solid electrolytes at modest sintering temperatures.

引用

页数：6

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