[Ge9{Si(SiMe3)3}2{Ge(SiMe3)3}]-: The Mixed Substituted Metalloid Germanium Cluster and the Intermetalloid Cluster [ZnGe18{Si(SiMe3)3}4{Ge(SiMe3)3}2]

被引：10

作者：

Kysliak, Oleksandr ^{[1
]}

Schnepf, Andreas ^{[1
]}

机构：

[1] Univ Tubingen, Chem Dept, Morgenstelle 18, D-72076 Tubingen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 03期

关键词：

Germyl groups; Germanium; Metalloid germanium cluster; Zinc; GE-9; CLUSTERS; ZINTL ION; REACTIVITY;

D O I：

10.1002/zaac.201800296

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel metalloid germanium cluster [Ge-9(Hyp)(2)Hyp(Ge)](-) (1) was synthesized, exhibiting two different bulky groups [Hyp = Si(SiMe3)(3); Hyp(Ge) = Ge(SiMe3)(3)]. Further reaction of 1 with ZnCl2 gives the derivative [ZnGe18(Hyp)(4)(Hyp(Ge))(2)] (2) in good yield, showing that the substitution of Si(SiMe3)(3) by Ge(SiMe3)(3) within a metalloid Ge9R3- compound leads to a comparable reactivity. 1 and 2 are characterized by NMR spectroscopy, mass spectrometry (1) and single crystal structure analyses (2). 1 and 2 are the first metalloid germanium clusters bearing germyl groups.

引用

页码：335 / 339

页数：5

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