One-Pot Synthesis of Luminescent Polymer-Nanoparticle Composites from Task-Specific Ionic Liquids

被引：26
|
作者：
Campbell, Paul S. [1 ]
Lorbeer, Chantal [1 ]
Cybinska, Joanna [1 ,2 ]
Mudring, Anja-Verena [1 ]
机构：
[1] Ruhr Univ Bochum, D-44780 Bochum, Germany
[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
ADVANCED FUNCTIONAL MATERIALS | 2013年 / 23卷 / 23期
基金：
欧洲研究理事会;
关键词：
luminescent polymers; lanthanide fluoride nanoparticles; microwave synthesis; nanoparticle-polymer composites; FLUORIDE NANOPARTICLES; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMERS; METAL NANOPARTICLES; OPTICAL-PROPERTIES; EXCITED-STATES; NANOCRYSTALS; CONVERSION; EMISSION; TEMPERATURE;
D O I：
10.1002/adfm.201202472
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A multifunctional polymerizable ionic liquid, diallyldimethylammonium tetrafluoroborate (DADMA BF4), is used in a one-pot synthesis of novel luminescent polymer-nanoparticle composites. First, small monodisperse lanthanide fluoride nanoparticles are formed by microwave irradiation in the presence of Ln(OAc)(3)center dot xH(2)O (Ln = Gd, Eu, Tb; OAc = acetate) in the ionic liquid. The nanoparticles can be precipitated for structural characterization or kept in the solution, which yields after irradition by high intensity UV light colorless, processable polymer materials with good photophysical properties. Both green-emitting Tb-containing and red-emitting Eu-containing IL- polymers are described.
引用
收藏
页码：2924 / 2931
页数：8
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