Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

被引：110

作者：

Igawa, Kazunobu ^{[1
]}

Yoshihiro, Daisuke ^{[2
]}

Ichikawa, Nobumasa ^{[2
]}

Kokan, Naoto ^{[3
]}

Tomooka, Katsuhiko ^{[1
]}

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan

[2] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Fukuoka 8168580, Japan

[3] Tokyo Inst Technol, Dept Appl Chem, Tokyo, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 51期

关键词：

asymmetric synthesis; enantioselectivity; hydrosilylation; ozone; silanes; ASYMMETRIC-SYNTHESIS; RACEMIC ACETYL(TERT-BUTYL)METHYLPHENYLSILANE; EFFICIENT APPROACH; SILICON; DERIVATIVES; HYDROSILYLATION; SILANES; COMPLEXES; KETONES; ALKYNES;

D O I：

10.1002/anie.201207361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric silanes: A synthesis of nonracemic alkenylhydrosilanes has been developed based on the desymmetrization of a dihydrosilane through alkenylation with an alkyne using an asymmetric catalyst. The alkenylhydrosilane product can be used as a versatile chiral building block for other functionalized nonracemic silanes through the stereoselective conversion of its hydride and/or alkenyl moiety. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12745 / 12748

页数：4

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