Synthesis of tertiary aryl amines of various aryl halides and secondary amines using ortho-palladated complex of tribenzylamine

被引：6
|
作者：
Hajipour, Abdol R. [1 ,2 ]
Dordahan, Fatemeh [1 ]
Rafiee, Fatemeh [1 ]
机构：
[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2013年 / 27卷 / 12期
关键词：
palladium catalyst; ortho-palladated complex; C?N cross-coupling reaction; PALLADIUM-CATALYZED AMINATION; CROSS-COUPLING REACTION; LIGANDS; CHLORIDE; SCOPE;
D O I：
10.1002/aoc.3044
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The activity of dimeric [Pd{C6H4(CH2N(CH2Ph)(2))} (-Br)](2) complex as an efficient, air- and moisture-tolerant catalyst was investigated in amination reactions of various aryl halides with secondary amines. Substituted tertiary aryl amines were produced in excellent yields and short reaction times using catalytic amounts of this dimeric complex in DMSO at 120 degrees C. Copyright (c) 2013 John Wiley & Sons, Ltd.
引用
收藏
页码：704 / 706
页数：3
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