Pb2+ and Cd2+ selective chemically modified field effect transistors based on thioamide functionalized 1,3-alternate calix[4]arenes

被引：41
|
作者：
Lugtenberg, RJW
Egberink, RJM
Engbersen, JFJ
Reinhoudt, DN
机构：
[1] UNIV TWENTE,FAC CHEM TECHNOL,LAB SUPRAMOL CHEM & TECHNOL,NL-7500 AE ENSCHEDE,NETHERLANDS
[2] UNIV TWENTE,FAC CHEM TECHNOL,MESA RES INST,NL-7500 AE ENSCHEDE,NETHERLANDS
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 07期
关键词：
D O I：
10.1039/a608063d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Novel calix[4]arenes fixed in the 1,3-alternate conformation and functionalized with thioamide groups have been synthesized and their selectivities for Pb2+ and Cd2+ ions in chemically modified field effect transistors (CHEMFETs)have been evaluated, The 5,27-bis(dimethylaminothiocarbonylmethoxy)-26, 28-dipropoxycalix[4]arene 3 in the 1,3-alternate conformation is more selective for Pb2+ than the analogous cone conformer, The 1,3-alternate calix[4]arene 8 having, in the 25- and 27-positions, two pairs of vicinal thioamide moieties at the same face of the molecule, has the highest selectivities for Cd2+ reported so far.
引用
收藏
页码：1353 / 1357
页数：5
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