Temperature-dependent nonradiative energy transfer from Gd3+ to Ce3+ ions in co-doped LuAG:Ce,Gd garnet scintillators

被引:35
|
作者
Onderisinova, Z. [1 ]
Kucera, M. [1 ]
Hanus, M. [1 ]
Nikl, M. [2 ]
机构
[1] Charles Univ Prague, Fac Math & Phys, CR-12116 Prague 2, Czech Republic
[2] AS CR, Inst Phys, Prague 16200 6, Czech Republic
关键词
Energy transfer; Scintillation; Multicomponent garnets; LuAG:Ce; Gd; Liquid phase epitaxy; LUAG EPITAXIAL-FILMS; RARE-EARTH IONS; SINGLE-CRYSTAL; LUMINESCENCE; MIGRATION; GROWTH; YAG; DIFFUSION; MECHANISM;
D O I
10.1016/j.jlumin.2015.06.014
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Energy transfer from donor Gd3+ to acceptor Ce3+ ions was studied in low doped lutetium aluminum garnet, LuAG:Ce,Gd. High purity single crystalline films were prepared by liquid phase epitaxy. The mechanism of nonradiative energy transfer from P-6(J) (Gd3+) multiplet to crystal field split (5)d(2) (D-2) states of Ce3+ was established as long-range dipole-dipole interaction and the average critical transfer distance between Gd3+ and Ce3+ ions was found similar to 14 angstrom at room temperature. It is shown that the single step energy transfer between donor-acceptor pairs is dominant while migration of excitation energy within the donor Gd3+ subsystem is only a small perturbation in the energy transfer mechanism in the studied low doped garnets. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:106 / 113
页数:8
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