Synthesis of atomic metal clusters on nanoporous alumina

被引：14

作者：

Peinetti, Ana Sol ^{[1
]}

Herrera, Santiago ^{[1
]}

Gonzalez, Graciela A. ^{[1
]}

Battaglini, Fernando ^{[1
]}

机构：

[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Inorgan Analit & Quim Fis, INQUIMAE, Buenos Aires, DF, Argentina

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 96期

关键词：

FLUORESCENT SILVER NANOCLUSTERS; NANOELECTRODE ARRAYS; GOLD CLUSTERS; LIGAND-EXCHANGE; MASS-TRANSPORT; SUBNANOMETER; ELECTRODEPOSITION; SIZE;

D O I：

10.1039/c3cc47170e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of atomic metal (gold and nickel) clusters by pulsed galvanostatic electrodeposition on nanoporous alumina is presented. The method allows the production of clusters with an average diameter of 0.7 nm for gold and 1.1 nm for nickel, while the size can be controlled through the current density applied. This strategy represents a simple and efficient method for the construction of heterogeneous catalysts and sub-nanometre electrode arrays exemplified here by the reduction of 4-nitrophenol and the electrochemical response to ferrocyanide.

引用

页码：11317 / 11319

页数：3

共 50 条

[21] Synthesis of Small Atomic Copper Clusters in Microemulsions
Vazquez-Vazquez, Carlos
Banobre-Lopez, Manuel
Mitra, Atanu
Arturo Lopez-Quintela, M.
Rivas, Jose
LANGMUIR, 2009, 25 (14) : 8208 - 8216
[22] Metal-oxide interaction for metal clusters on a metal-supported thin alumina film
Andersson, S
Brühwiler, PA
Sandell, A
Frank, M
Libuda, J
Giertz, A
Brena, B
Maxwell, AJ
Bäumer, M
Freund, HJ
Mårtensson, N
SURFACE SCIENCE, 1999, 442 (01) : L964 - L970
[23] Fragmentation phase transition in atomic clusters II - Symmetry of fission of metal clusters
Madjet, ME
Hervieux, PA
Gross, DHE
Schapiro, O
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1997, 39 (04): : 309 - 316
[24] Finding atomic dynamics in metal and alloy subnanometer clusters
Imaoka, Takane
Yamamoto, Kimihisa
CHEMISTRY LETTERS, 2024, 53 (08)
[25] Magnetic anisotropies of late transition metal atomic clusters
Fernandez-Seivane, Lucas
Ferrer, Jaime
PHYSICAL REVIEW LETTERS, 2007, 99 (18)
[26] THE COLOR OF METAL-CLUSTERS AND OF ATOMIC-NUCLEI
BROGLIA, RA
CONTEMPORARY PHYSICS, 1994, 35 (02) : 95 - 104
[27] EVAPORATION OF HOT MESOSCOPIC ATOMIC METAL-CLUSTERS
HERVIEUX, PA
GROSS, DHE
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1995, 33 (04): : 295 - 299
[28] Quantum algebraic symmetries in atomic nuclei and metal clusters
Bonatsos, D
Kotsos, BA
Raychev, PP
Terziev, PA
GROUP 24 : PHYSICAL AND MATHEMATICAL ASPECTS OF SYMMETRIES, 2003, 173 : 387 - 390
[29] STATISTICAL FRAGMENTATION OF HOT ATOMIC METAL-CLUSTERS
GROSS, DHE
HERVIEUX, PA
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1995, 35 (01): : 27 - 42
[30] Enhancing the platinum atomic layer deposition infiltration depth inside anodic alumina nanoporous membrane
Vaish, Amit
Krueger, Susan
Dimitriou, Michael
Majkrzak, Charles
Vanderah, David J.
Chen, Lei
Gawrisch, Klaus
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2015, 33 (01):

← 1 2 3 4 5 →