Studies of crystallization of SAPO-11 molecular sieve and applications for catalytic skeletal isomerization of linear butylenes

被引：0
|
作者：
Tian, HP [1 ]
Li, CL [1 ]
机构：
[1] E CHINA UNIV SCI & TECHNOL, PETR PROC RES CTR, SHANGHAI 200237, PEOPLES R CHINA
来源：
PROGRESS IN ZEOLITE AND MICROPOROUS MATERIALS, PTS A-C | 1997年 / 105卷
关键词：
crystallization; SAPO-11; catalysis; skeletal isomerization;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
SAPO-11 molecular sieve has been synthesized at 443-473K from mixtures of AlPO4, H3PO4 and SiO2 sol-gel with i-Pr2NH as a templating agent. Synthesis process is found to be influenced by molar compositions of sol-gel mixtures, crystallization temperatures and periods, and is evaluated by applying Avrami equation and Arrhenius equation. Crystalline products have been used in catalytic skeletal isomerization of linear butylenes. The variance of activity with framework composition of SAPO-11 molecular sieve is discussed.
引用
收藏
页码：1397 / 1404
页数：8
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