Intrinsic chemistry of [OUCH]+: reactions with H2O, CH3CN and O2

被引：9

作者：

Metzler, Luke J. ^{[1
]}

Farmen, Christopher T. ^{[1
]}

Corcovilos, Theodore A. ^{[2
]}

Van Stipdonk, Michael J. ^{[1
]}

机构：

[1] Duquesne Univ, Dept Chem & Biochem, 600 Forbes Ave, Pittsburgh, PA 15282 USA

[2] Duquesne Univ, Dept Phys, 600 Forbes Ave, Pittsburgh, PA 15282 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2021年 / 23卷 / 08期

关键词：

D O I：

10.1039/d1cp00177a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the first experimental study of the intrinsic chemistry of a U-methylidyne species, focusing on reaction of [OUCH](+) with H2O, O-2 and CH3C N in the gas phase. DFT was also used to determine reaction pathways, and establish the mechanism by which [OUCH](+) is formed through collision-induced dissociation of [UO2(C CH)](+).

引用

页码：4475 / 4479

页数：5

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