Fisher information and kinetic energy functionals: A dequantization approach

被引:14
|
作者
Hamilton, I. P. [1 ]
Mosna, Ricardo A. [2 ]
机构
[1] Wilfrid Laurier Univ, Dept Chem, Waterloo, ON N2L 3C5, Canada
[2] Univ Estadual Campinas, Inst Matemat Estatist & Computacao Cient, BR-13083859 Campinas, SP, Brazil
关键词
Fisher information; Kinetic energy functionals; Dequantization; SYSTEMS;
D O I
10.1016/j.cam.2009.02.087
中图分类号
O29 [应用数学];
学科分类号
070104 ;
摘要
We strengthen the connection between information theory and quantum-mechanical systems using a recently developed dequantization procedure whereby quantum fluctuations latent in the quantum momentum are suppressed. The dequantization procedure results in a decomposition of the quantum kinetic energy as the sum of a classical term and a purely quantum term. The purely quantum term, which results from the quantum fluctuations, is essentially identical to the Fisher information. The classical term is complementary to the Fisher information and, in this sense, it plays a role analogous to that of the Shannon entropy. We demonstrate the kinetic energy decomposition for both stationary and nonstationary states and employ it to shed light on the nature of kinetic energy functionals. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1542 / 1547
页数:6
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