Thiolate Complexes Catalyst in Noble-Metal-Free System for Light-driven Hydrogen Production

被引：0
|
作者：
Li, Guang-Yan [1 ]
Fu, Da-Tian [2 ]
Cai, Xiu-Lan [1 ]
机构：
[1] Guangdong Pharmaceut Univ, Guangzhou, Guangdong, Peoples R China
[2] Hainan Canc Hosp, Haikou, Hainan, Peoples R China
来源：
PROCEEDINGS OF THE 4TH 2016 INTERNATIONAL CONFERENCE ON MATERIAL SCIENCE AND ENGINEERING (ICMSE 2016) | 2016年 / 101卷
关键词：
Fe thiolate complexes; Photocatalysis; Hydrogen; VISIBLE-LIGHT; WATER; REDUCTION; EFFICIENT; ENERGY; SOLAR;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this paper, Fe thiolate complexes Fe(phen(pyS)(2) (M) were synthesized and the properties of complexes were characterized by H-1-NMR and MS. The effects of reaction conditions on performanceof Fe thiolate complexes Fe(phen(pyS)(2)had been studied. The results of catalytic performance implied thatwhen 2.0 mMfluorescein was used as photosensitizer, ethanol/water was used as solvent and its volume ratio of ethanol/water was 1:1, catalyst M showed the highest catalytic performance and hydrogen production was 115.6 mu mol/h after reacted for 15 h.
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页码：25 / 29
页数：5
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