Vanadium-catalyzed deoxydehydration of glycols

被引：83
|
作者：
Chapman, Garry, Jr. [1 ]
Nicholas, Kenneth M. [1 ]
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期
基金：
美国国家科学基金会;
关键词：
STATE PROPERTIES; SULFITE-DRIVEN; BIOMASS; CONVERSION; DIOLS; DEOXYGENATION; DERIVATIVES; MECHANISM; ALCOHOLS; ALKENES;
D O I：
10.1039/c3cc44656e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A survey of several metavandate (VO3-) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(v)-dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenyl-phosphine or sodium sulfite as reductants.
引用
收藏
页码：8199 / 8201
页数：3
相关论文
共 50 条
  • [21] Theoretical study of vanadium-catalyzed butane oxidation
    Shimizu, R
    Fuchikami, T
    CATALYSIS TODAY, 2001, 71 (1-2) : 137 - 143
  • [22] Vanadium-Catalyzed Condensation of Ethyl Cyanoacetate with Ketones
    Khusnutdinov, R. I.
    Shchadneva, N. D.
    Mayakova, Yu. Yu.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2018, 88 (03) : 403 - 409
  • [23] Recent advances in enantioselective vanadium-catalyzed transformations
    Pellissier, Helene
    COORDINATION CHEMISTRY REVIEWS, 2015, 284 : 93 - 110
  • [24] Vanadium-catalyzed pinacol coupling reaction in water
    Xu, XL
    Hirao, T
    JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (21): : 8594 - 8596
  • [25] Vanadium-Catalyzed Condensation of Ethyl Cyanoacetate with Ketones
    R. I. Khusnutdinov
    N. А. Shchadneva
    Yu. Yu. Mayakova
    Russian Journal of General Chemistry, 2018, 88 : 403 - 409
  • [26] Vanadium-catalyzed addition of propargyl alcohols and imines
    Trost, Barry M.
    Chung, Cheol K.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (32) : 10358 - 10359
  • [27] Copper- and vanadium-catalyzed asymmetric oxidations
    Bolm, C
    Schlingloff, G
    Bienewald, F
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 117 (1-3) : 347 - 350
  • [28] Vanadium-catalyzed asymmetric epoxidation of homoallylic alcohols
    Zhang, Wei
    Yamamoto, Hisashi
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (02) : 286 - 287
  • [29] A Vanadium-Catalyzed Synthesis of Fully Substituted Pyrroles
    Paciorek, Patrycja
    Szklarzewicz, Janusz
    Trzewik, Bartosz
    Ciez, Dariusz
    Nitek, Wojciech
    Hodorowicz, Maciej
    Jurowska, Anna
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (02): : 1649 - 1658
  • [30] Vanadium-catalyzed enantioselective oxidation of allyl sulfides
    Zeng, Qingle
    Gao, Yuxing
    Dong, Junyu
    Weng, Wen
    Zhao, Yufen
    TETRAHEDRON-ASYMMETRY, 2011, 22 (07) : 717 - 721
12345