Vanadium-catalyzed deoxydehydration of glycols

被引：83
|
作者：
Chapman, Garry, Jr. [1 ]
Nicholas, Kenneth M. [1 ]
机构：
[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期
基金：
美国国家科学基金会;
关键词：
STATE PROPERTIES; SULFITE-DRIVEN; BIOMASS; CONVERSION; DIOLS; DEOXYGENATION; DERIVATIVES; MECHANISM; ALCOHOLS; ALKENES;
D O I：
10.1039/c3cc44656e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A survey of several metavandate (VO3-) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(v)-dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenyl-phosphine or sodium sulfite as reductants.
引用
收藏
页码：8199 / 8201
页数：3
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