Superhydrophobic coatings with high repellency to daily consumed liquid foods based on food grade waxes

被引:78
|
作者
Zhao, Xia [1 ]
Hu, Tao [1 ,2 ]
Zhang, Junping [2 ]
机构
[1] Lanzhou Univ Technol, Dept Chem Engn, Coll Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China
[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Clay Mineral Appl Res Gansu Prov, Lanzhou 730000, Gansu, Peoples R China
关键词
Superhydrophobicity; Self-cleaning; Wettability; Anti-adhesion; Contact angle; LOTUS-LEAF; SURFACES; FABRICATION; SPRAY; NANOCOMPOSITES; WETTABILITY; SEPARATION; FILMS; WATER; ELECTRODEPOSITION;
D O I
10.1016/j.jcis.2018.01.034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The applications of superhydrophobic coatings in daily life are receiving increasing attention. Here, we report a general approach for preparing superhydrophobic coatings with high repellency to daily consumed liquid foods based on food grade waxes. The coatings are prepared by spray-coating the homogeneous wax suspensions in ethanol followed by annealing at 40 degrees C. The wax suspensions are formed by the heating dissolution-cooling precipitation-ultrasonication process thanks to the unique solubility of the waxes in ethanol. Ultrasonication of the wax suspension is helpful to improve superhydrophobicity by reducing the size of the wax microplatelets. Annealing at 40 degrees C could enhance mechanical stability of the coatings. The coatings are superhydrophobic with a water contact angle of 158.2 degrees and a sliding angle of 7.3 degrees. The coatings are resistant to intense water jetting and immersion in corrosive aqueous solutions. In addition, the coatings show excellent anti-adhesive properties for various liquid foods including cola, honey, milk and yoghourt. Moreover, the coatings are applicable onto different substrates (e.g., glass slide, PET plate and polyethylene plate) and could be prepared using different waxes (e.g., paraffin wax, beeswax and microcrystalline wax). We believe that the wax superhydrophobic coatings could find applications in various fields such as anti-adhesion of liquid foods, fruit preservation and antibioadhesion, etc. (C) 2018 Elsevier Inc. All rights reserved.
引用
收藏
页码:255 / 263
页数:9
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