Synthesis, growth, structure and characterization of a new semiorganic crystal

被引：4
|
作者：
Rajasekar, M. [1 ]
Muthu, K. [1 ]
Meenatchi, V. [1 ]
Meenakshisundaram, S. P. [1 ]
Mojumdar, S. C. [2 ,3 ]
机构：
[1] Annamalai Univ, Dept Chem, Annamalainagar 608002, Tamil Nadu, India
[2] Univ Trencin, Dept Mat Technol & Environm, Fac Ind Technol Puchov, Puchov 02001, Slovakia
[3] Univ Guelph, Dept Chem, Guelph, ON N1G 2W1, Canada
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 112卷 / 02期
关键词：
Allylthiourea complex; Thermal analysis; Mechanical studies; X-ray diffraction; Optical studies; COORDINATION COMPLEX CRYSTAL; ORGANIC-INORGANIC CRYSTAL; OPTICAL-PROPERTIES; THERMAL-ANALYSIS; TRANSPORT; MG(II); ATCC;
D O I：
10.1007/s10973-013-3101-8
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A new semiorganic single crystal, tris(allylthiourea)silver(I) nitrate was grown from an aqueous solution containing silver(I) nitrate and allylthiourea by slow evaporation solution growth technique at room temperature. The crystal belongs to trigonal system with centrosymmetric space group R3 and the cell parameters are, a = 12.5090(4) , b = 12.5090(4) , c = 21.7130(8) , V = 3348.89 (3), and Z = 6. The various functional groups present in the molecule are confirmed by Fourier transformed infrared spectroscopy. High transmittance is observed in the visible region and band-gap energy is calculated by Kubelka-Munk algorithm. The structure and the crystallinity of the materials were further confirmed using powder X-ray diffraction analysis. Microhardness studies were also carried out to elucidate the mechanical behavior. Thermogravimetric and differential thermal analysis reveal the purity of the sample and no decomposition is observed up to the melting point.
引用
收藏
页码：1107 / 1112
页数：6
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