Preparation and properties of waterborne polyurethaneurea consisting of fluorinated siloxane units

被引:33
|
作者
Su, T
Wang, GY
Xu, XD
Hu, CP [1 ]
机构
[1] Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China
关键词
aqueous dispersions; fluorinated polysiloxanes; FT-IR; mechanical properties; phase separation; water resistance; waterborne polyurethaneurea;
D O I
10.1002/pola.21425
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of polyurethaneurea (PUU) aqueous dispersions were prepared via a prepolymer process from polyester polyol, alpha,omega-dihydroxypolyl[(3,3,3-trifluoropropyl) methylsiloxane] (PTFPMS), dimethylolpropionic acid, isophorone diisocyanate, and ethylenediamine. These anionic-type aqueous dispersions were stable at the ambient temperature for more than 6 months, with particle sizes ranging from 69 to 127 nm. For these aqueous dispersions, the surface tension decreased with increasing PTFPMS content, but the particle size increased with a maximum value. The film prepared from the PUU aqueous dispersion consisting of 5 wt % PTFPMS (APU-FS-5) exhibited excellent waterproof performance. Furthermore, the tensile strength of the APU-FS-5 film increased nearly 3 times compared with that of the PUU film without PTFPMS, whereas the elongation at break only decreased a little; this indicated that the water-resistant and mechanical properties could be enhanced markedly and simultaneously for the PUU films containing both silicon and fluorine groups. The experimental results showed a high degree of hydrogen bonding for urea groups and an increased microphase-separation degree between the hard and soft segments in the PTFPMS-modified system, which resulted in the excellent mechanical properties of these films.
引用
收藏
页码:3365 / 3373
页数:9
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