Study on the Reaction Characteristics of Directional Synthesis of α-Terpineol from Turpentine

被引：1
|
作者：
Gu, Yan [1 ]
Zhao, Zhendong [1 ]
Song, Jie
Li, Dongmei [1 ]
Wang, Jing
Lu, Yanju
Bi, Liangwu [1 ]
机构：
[1] CAF, Inst New Technol, Nanjing 210042, Jiangsu, Peoples R China
来源：
ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5 | 2013年 / 634-638卷
关键词：
alpha-terpineol; gamma-terpineol; stereochemistry structure; thermodynamic analysis; reaction mechanism;
D O I：
10.4028/www.scientific.net/AMR.634-638.424
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
There was rarely high-purity alpha-terpineol or pure-monomer alpha-terpineol in China due to difficulty in isolating alpha-terpineol and gamma-terpineol. Aiming at the separation problem, alpha-terpineol was directional synthesized by one-step method in a uniform system. The influence factors of stereochemistry structure, thermodynamic analysis and stability of reactants, products and carbocations were researched, conducting the experiments in optimal reaction conditions. All the influence factors about generating trend of objective product alpha-terpineol and byproduct gamma-terpineol were discussed and the reaction mechanism was studied. This paper provided certain theoretical basis on prepare high-purity alpha-terpineol.
引用
收藏
页码：424 / 432
页数：9
相关论文
共 50 条
  • [41] Synthesis of Directional Wave Packets from Shot Records
    Ding, Yinshuai
    Zhou, Hua-Wei
    Zheng, Yingcai
    Wo, Yukai
    PURE AND APPLIED GEOPHYSICS, 2019, 176 (10) : 4321 - 4333
  • [42] Synthesis of cyclopentane derivatives as perfumery materials from turpentine(II) - synthesis of cyclopentane hydroxy ketone from 1,2,8-menthanetriol
    Qin, Xiaolin
    Chen, Youdi
    He, Youren
    Linchan Huaxue Yu Gongye/Chemistry and Industry of Forest Products, 1998, 18 (03):
  • [43] Synthesis of cyclopentane derivatives as perfumery materials from turpentine (2). Synthesis of cyclopentane hydroxy ketone from 1,2,8-menthanetriol
    Qin, Xiaolin
    Chen, Youdi
    He, Youren
    Li, Xiuling
    Chung-kuo Tsao Chih/China Pulp and Paper, 1998, 17 (05): : 1 - 10
  • [44] Study on Reaction Process of Synthesis of Indole from Aniline and Ethylene Glycol
    Xing, Junde
    Liu, Zhi
    APPLICATIONS OF ENGINEERING MATERIALS, PTS 1-4, 2011, 287-290 : 120 - 123
  • [45] DIRECTIONAL CHARACTERISTICS OF METEOR PROPAGATION DERIVED FROM RADAR MEASUREMENTS
    ESHLEMAN, VR
    MLODNOSKY, RF
    PROCEEDINGS OF THE INSTITUTE OF RADIO ENGINEERS, 1957, 45 (12): : 1715 - 1723
  • [46] Directional characteristics of near infrared light reflected from wood
    Tsuchikawa, S
    Torii, M
    Tsutsumi, S
    HOLZFORSCHUNG, 2001, 55 (05) : 534 - 540
  • [47] DIRECTIONAL CHARACTERISTICS OF THERMAL RADIATION EMITTED FROM MICROSTRUCTURED SURFACE
    Hirashima, Daisuke
    Hanamura, Katsunori
    VI. PROCEEDINGS OF THE 6TH INTERNATIONAL SYMPOSIUM ON RADIATIVE TRANSFER (RADIATIVE TRANSFER), 2010,
  • [48] DIRECTIONAL CHARACTERISTICS OF THERMAL RADIATION EMITTED FROM MICROSTRUCTURED SURFACE
    Hirashima, Daisuke
    Hanamura, Katsunori
    VI. PROCEEDINGS OF THE 6TH INTERNATIONAL SYMPOSIUM ON RADIATIVE TRANSFER (RADIATIVE TRANSFER), 2010,
  • [49] SYNTHESIS OF LINALOOL AND 4-TERPINEOL FROM [C-14] MEVALONIC ACID IN PINUS-PINASTER
    MACHADO, A
    GARCIAPE.E
    MAYOR, F
    PLANT SCIENCE LETTERS, 1974, 2 (02): : 83 - 87
  • [50] SYNTHESIS OF STEP DIRECTIONAL-COUPLERS WITH NON-MINIMUM PHASE CHARACTERISTICS
    GORBACHEV, AP
    NEVEROV, SG
    RADIOTEKHNIKA I ELEKTRONIKA, 1984, 29 (08): : 1479 - 1486
12345