A Photochromic Diarylethene with Five and Six-membered Aryl Units

被引：0
|
作者：
Tong, Zhipeng [1 ]
Pu, Shouzhi [1 ]
Cui, Shiqiang [1 ]
机构：
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源：
ADVANCES IN MATERIALS SCIENCE-BOOK | 2011年 / 327卷
关键词：
Diarylethene; Synthesis; Photochromism; Fluorescence; FLUORESCENCE;
D O I：
10.4028/www.scientific.net/AMR.327.37
中图分类号：
TP301 [理论、方法];
学科分类号：
081202 ;
摘要：
A photochromic diarylethene bearing a six-membered aryl unit 1-[(2,5-dimethyl-3-thienyl)]-2[2-methy-4-(3,5-difluorophenyl)-phenyl]perfluoroyclopentene (1a) was synthesized and its photochromic and fluorescent properties were also investigated in detail. The results showed that this compound exhibited reversible photochromism, changing from colorless to red after irradiation with UV light, in which absorption maxima were observed at 521 and 536nm in hexane and PMMA film, respectively. The fluorescence intensity decreased along with the photochromism upon irradiation with 297 nm light in hexane.
引用
收藏
页码：37 / 40
页数：4
相关论文
共 50 条
  • [41] Synthesis of Five and Six-Membered Heterocycles Using Activated Nitriles for Industrial Applications
    El-Sayed, Refat
    Almalki, Meshal H. K.
    JOURNAL OF OLEO SCIENCE, 2017, 66 (08) : 925 - 938
  • [42] Application of the cyano ester ring closure to five- and six-membered rings
    Fuson, RC
    Cole, W
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 : 1237 - 1239
  • [43] SYNTHESIS OF FIVE- AND SIX-MEMBERED HETEROCYCLIC COMPOUNDS BY THE APPLICATION OF THE METATHESIS REACTIONS
    Majumdar, Krishna C.
    Muhuri, Sanjukta
    Islam, Rarique Ul
    Chattopadhyay, Buddhadeb
    HETEROCYCLES, 2009, 78 (05) : 1109 - 1169
  • [44] Cyclic silylhydrazines -: Crystal structures of isomeric five- and six-membered rings
    Gellermann, E
    Klingebiel, U
    Witte-Abel, H
    Schäfer, M
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2000, 55 (06): : 504 - 510
  • [45] Four-, five-, and six-membered silylhydrazine-ring systems
    Dielkus, S.
    Drost, C.
    Herbst-Irmer, R.
    Klingebiel, U.
    Pauer, F.
    Organometallics, 1994, 13 (10)
  • [46] Group 13 five- and six-membered rings with rare 2π aromaticity
    Huo, Yutong
    Gu, Xiaojiao
    Li, Xinde
    Jin, Peng
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 26 (01) : 342 - 351
  • [47] Application of 2-Aminopyridines in the Synthesis of Five- and Six-Membered Azaheterocycles
    Chen, Qi
    Chen, Sihong
    Wu, Hanqing
    Zeng, Xiaoqing
    Chen, Weiqing
    Sun, Guoxing
    Wang, Zhaoyang
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (09) : 3482 - 3491
  • [48] Cyclic silylhydrazines - Crystal structures of isomeric five- and six-membered rings
    Gellermann, Eike
    Klingebiel, Uwe
    Witte-Abel, Henning
    Schäfer, Martina
    Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2000, 55 (06): : 504 - 510
  • [49] On the competition between six-membered and five-membered NHC towards alane centered ring expansion
    Balayan, Kajal
    Sharma, Himanshu
    Vanka, Kumar
    Ravindranathan, Sapna
    Gonnade, Rajesh G.
    Sen, Sakya S.
    CHEMICAL COMMUNICATIONS, 2023, 59 (55) : 8540 - 8543
  • [50] NEW DEVELOPMENTS IN THE SYNTHESIS OF SACCHARIN RELATED FIVE- AND SIX-MEMBERED BENZOSULTAMS
    Liu, Zhaopeng
    Takeuchi, Yoshio
    HETEROCYCLES, 2009, 78 (06) : 1387 - 1412
12345