Two polymorphs of tris(ethylenediamine)cobalt(III) tetrathioantimonate(V)

被引：4

作者：

Wang, Ming-Feng ^{[1
]}

Yue, Cheng-Yang ^{[1
]}

Yuan, Zhuang-Dong ^{[1
]}

Lei, Xiao-Wu ^{[1
]}

机构：

[1] Jining Univ, Dept Chem & Chem Engn, Key Lab Inorgan Chem Univ Shandong, Qufu 273155, Shandong, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2013年 / 69卷

基金：

中国国家自然科学基金;

关键词：

crystal structure; polymorphs; cobalt complexes; chalcogenides; thioantimonates; SULFIDE;

D O I：

10.1107/S0108270113017277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Details of the structures of two polymorphs of tris(ethylenediamine) cobalt(III) tetrathioantimonate(V), [Co(C2H8N2)(3)][SbS4], are reported. The first polymorph crystallizes in the orthorhombic space group Pna2(1), whereas the second polymorph belongs to the tetragonal space group P4(2)bc. Both structures contain octahedral [Co(en)(3)](3+) cations (en is ethylenediamine) and tetrahedral [SbS4](3) anions, which are interconnected via various N-H center dot center dot center dot S hydrogen bonds to form two different types of three-dimensional network.

引用

页码：855 / 858

页数：4

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