Kinetic modeling and optimization of operating parameters for transvinylation of lauric acid

被引：2
|
作者：
Kamble, Sanjay P. [1 ]
Manjarekar, Onkar [1 ]
Mawale, Ravi [1 ]
Kulkarni, Bhaskar D. [1 ]
Chowdary, Naresh [1 ]
Gupte, Milind Y. [1 ]
Barve, Prashant P. [1 ]
机构：
[1] Natl Chem Lab CSIR NCL, Chem Engn & Proc Dev Div, Pune 411008, Maharashtra, India
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 2012年 / 44卷 / 09期
关键词：
D O I：
10.1002/kin.20704
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The transition metal complex catalyzed transvinylation of carboxylic acid with vinyl acetate monomer is of significant interest to industry. The palladium complex catalyzed transvinylation of lauric acid using vinyl acetate monomer is a reversible reaction. In present article, design of experiments (DOE) statistics is used to study effects of various operating parameters on transvinylation of lauric acid. The kinetic parameters forward and backward rate constants and the thermodynamic parameters such as equilibrium constant and energy of activation of the transvinylation of lauric acid were estimated using the Dynochem model. The optimum operating parameters for the transvinylation of lauric acid were then predicted using the Dynochem model and verified by performing the actual experiments to validate the model. It was found that the experimental results match with the predicted one. (c) 2012 Wiley Periodicals, Inc. Int J Chem Kinet 44: 624634, 2012
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收藏
页码：624 / 634
页数：11
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