Rh(III)-catalyzed directed C-H bond amidation of ferrocenes with isocyanates

被引：39

作者：

Takebayashi, Satoshi ^{[1
]}

Shizuno, Tsubasa ^{[1
]}

Otani, Takashi ^{[1
]}

Shibata, Takanori ^{[1
]}

机构：

[1] Waseda Univ, Dept Chem & Biochem, Sch Adv Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 8卷

基金：

日本学术振兴会;

关键词：

amidation; C-H activation; C-H functionalization; ferrocene; rhodium; ASYMMETRIC CATALYSIS; ARYL; ACTIVATION; INSERTION; IMINES; RH;

D O I：

10.3762/bjoc.8.212

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[RhCp*(OAc)(2)(H2O)] [Cp* = pentamethylcyclopentadienyl] catalyzed the C-H bond amidation of ferrocenes possessing directing groups with isocyanates in the presence of 2 equiv/Rh of HBF4 center dot OEt2. A variety of disubstituted ferrocenes were prepared in high yields, or excellent diastereoselectivities.

引用

页码：1844 / 1848

页数：5

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