Green synthesis of tertiary alkylselanylphosphine chalcogenides via catalyst- and solvent-free addition of secondary phosphine chalcogenides to vinyl selenides

被引：8
|
作者：
Gusarova, N. K. [1 ]
Chernysheva, N. A. [1 ]
Yas'ko, S. V. [1 ]
Trofimov, B. A. [1 ]
机构：
[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664003, Russia
来源：
JOURNAL OF SULFUR CHEMISTRY | 2015年 / 36卷 / 05期
关键词：
secondary phosphine chalcogenides; vinyl selenides; addition reaction; synthesis; alkylselanylethylphosphine chalcogenides; ORGANOPHOSPHORUS COMPOUNDS; CONVENIENT SYNTHESIS; ALKENES; HYDROPHOSPHINATION; COMPLEXES; SULFIDES; ALKYNES;
D O I：
10.1080/17415993.2015.1066375
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Secondary phosphine sulfides and phosphine selenides react with vinyl selenides under mild conditions (80-82 degrees C, without catalyst and solvent) to form regioselectively functionalized anti-Markovnikov adducts in high yield.
引用
收藏
页码：526 / 534
页数：9
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