Green synthesis of tertiary alkylselanylphosphine chalcogenides via catalyst- and solvent-free addition of secondary phosphine chalcogenides to vinyl selenides

被引：8

作者：

Gusarova, N. K. ^{[1
]}

Chernysheva, N. A. ^{[1
]}

Yas'ko, S. V. ^{[1
]}

Trofimov, B. A. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664003, Russia

来源：

JOURNAL OF SULFUR CHEMISTRY | 2015年 / 36卷 / 05期

关键词：

secondary phosphine chalcogenides; vinyl selenides; addition reaction; synthesis; alkylselanylethylphosphine chalcogenides; ORGANOPHOSPHORUS COMPOUNDS; CONVENIENT SYNTHESIS; ALKENES; HYDROPHOSPHINATION; COMPLEXES; SULFIDES; ALKYNES;

D O I：

10.1080/17415993.2015.1066375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Secondary phosphine sulfides and phosphine selenides react with vinyl selenides under mild conditions (80-82 degrees C, without catalyst and solvent) to form regioselectively functionalized anti-Markovnikov adducts in high yield.

引用

页码：526 / 534

页数：9

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