Cyclization-Induced Turn-On Fluorescence System Applicable to Dicarboxylate Sensing

被引：52
|
作者：
Noguchi, Takao [1 ,2 ]
Roy, Bappaditya [1 ]
Yoshihara, Daisuke [2 ]
Tsuchiya, Youichi [2 ]
Yamamoto, Tatsuhiro [2 ]
Shinkai, Seiji [1 ,2 ,3 ]
机构：
[1] Kyushu Univ, Inst Adv Study, Nishi Ku, Fukuoka 8190395, Japan
[2] Inst Syst Informat Technol & Nanotechnol ISIT, Nanotechnol Lab, Nishi Ku, Fukuoka 8190388, Japan
[3] Sojo Univ, Fac Engn, Dept Nanosci, Kumamoto 8600082, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 02期
关键词：
cooperativity; dicarboxylic acid; fluorescence; molecular recognition; nonlinear response; MOLECULAR RECOGNITION; ANION RECOGNITION; TETRAPHENYLETHYLENE; RECEPTORS; BINDING; ACIDS;
D O I：
10.1002/chem.201304031
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel tetraphenylethene-based fluorescence (FL) chemosensor exhibits nonlinear turn-on FL switching though cooperative binding of l-tartarate, where its convergent binding to form cyclic substructures is responsible for the FL increase. This binding scheme achieves selective detection of dicarboxylates over monocarboxylates, thus is potentially applicable to the preliminary screening for metabolic disorders.
引用
收藏
页码：381 / 384
页数：4
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