One-dimensional cobalt and zinc complexes involving in situ reaction of ethylenediamine and acetonitrile to form imidazoline ligand

被引:13
|
作者
Hao, ZM [1 ]
Zhang, XM [1 ]
机构
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
imidazoline; ligand reaction;
D O I
10.1016/j.inoche.2005.10.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The solvothermal treatment of cobalt nitrate (or zinc acetate), ethylenediamine and dicarboxylate in acetonitrile produced two one-dimensional coordination polymers [Co(mimz)(2)(ox)](n) (1) and [Zn(mimz)(2)(ip)](n) (2) (mimz = 2-methylimidazoline, ox = oxalate, ip = isophthalate) which ligand involving in situ formation of imidazoline ligand by cycloaddition reaction of ethylenediamine and acetonitrile. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:57 / 59
页数:3
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