Syntheses, crystal structure, and fluorescent properties of a lanthanide complex

被引：0
|
作者：
Zhao, X. H. [1 ]
Peng, H. M. [1 ]
机构：
[1] Hunan Univ Technol, Key Lab Green Packaging & Applicat Biol Nanotechn, Zhuzhou 412008, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 01期
关键词：
SECONDARY BUILDING UNITS; COORDINATION POLYMERS; NEODYMIUM(III); NETWORK;
D O I：
10.1134/S1070328412110085
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new complex [Dy-2(Pht)(2)(HPht)(2)(Phen)(2)(H2O)(4)] (I), where Pht(2-) = dianion of o-phthalic acid; HPht(-) = mono-anion of o-phthalic acid; Phen = 1,10-phenanthroline, has been synthesized and the crystal structure was determined by X-ray crystallography. The I crystallizes in the triclinic system, space group with lattice parameters a =10.1126(3) , b =10.7029(3) , c = 11.9360(3) , alpha = 90.2260(10)A degrees, beta = 99.5340(10)A degrees, gamma = 100.9810(10)A degrees, V = 1249.87(6) (3), Z = 2, rho(calcd) = 1.881 mg m(-3). The photophysical property of I has been studied with excitation and emission spectra.
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页码：126 / 129
页数：4
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