Kinetics of dispersion polymerization of styrene in ethanol .2. Model validation

被引：25
|
作者：
Ahmed, SF
Poehlein, GW
机构：
[1] School of Chemical Engineering, Georgia Institute of Technology, Atlanta
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1997年 / 36卷 / 07期
关键词：
D O I：
10.1021/ie960506j
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Predictions of monomer conversion, polymerization rate, and evolution of particle size distribution during seeded batch and continuous dispersion polymerization obtained from simulation are compared to experimental results. An understanding of the kinetic mechanisms governing the relative prevalence of solution and microbulk polymerization has been gained. Estimates of parameters in the radical transport rate coefficient models compare favorably-with values reported in the literature.
引用
收藏
页码：2605 / 2615
页数：11
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