Indium-Catalyzed Friedel-Crafts Alkylation of Monosubstituted Benzenes by 1-Bromoadamantane

被引：13

作者：

Mosset, Paul ^{[1
]}

Gree, Rene ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Sci Chim Rennes, CNRS UMR 6226, F-35042 Rennes, France

来源：

SYNLETT | 2013年 / 24卷 / 09期

关键词：

adamantanes; alkylation; catalysis; indium; Lewis acids; MULTIVALENT SCAFFOLDS; RUTHENIUM CATALYSTS; ARYL; CHLORIDES; EFFICIENT; LIGANDS; ADAMANTYLATION; SUBSTITUTION; ADAMANTANE; ARYLATION;

D O I：

10.1055/s-0032-1316909

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium salts such as InCl3 and InBr3 (ca. 1-5 mol%) efficiently catalyzed the Friedel-Crafts reaction of 1-bromoadamantane with benzene and monosubstituted benzenes to give 1-adamantyl benzenes. Indium bromide enabled faster reactions than indium chloride but the latter was more suitable in the case of halobenzenes.

引用

页码：1142 / 1146

页数：5

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