Current oscillations during CO electro-oxidation on smooth platinum

被引：5
|
作者：
Azevedo, DC [1 ]
Pinheiro, ALN [1 ]
Gonzalez, ER [1 ]
机构：
[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
ELECTROCHEMICAL AND SOLID STATE LETTERS | 2002年 / 5卷 / 03期
关键词：
D O I：
10.1149/1.1450062
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In this paper it is shown, for the first time, the presence of current oscillations in the electro-oxidation of carbon monoxide on a rotating platinum electrode. The current oscillations occur in a very restricted potential region around 950 mV vs. reversible hydrogen electrode, and may be observed for over 12 h. They are discussed in terms of the mechanism for CO electro-oxidation and the mutual influence of the processes of CO adsorption and formation of oxygenated species on the surface. (C) 2002 The Electrochemical Society.
引用
收藏
页码：A51 / A54
页数：4
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