Mechanism of corrosion of zirconium hydride and impact of precipitated hydrides on the Zircaloy-4 corrosion behaviour

被引：31
|
作者：
Tupin, M. [1 ]
Bisor, C. [1 ]
Bossis, P. [1 ]
Chene, J. [2 ]
Bechade, J. L. [3 ]
Jomard, F. [4 ]
机构：
[1] CEA, DEN, Serv Etud Mat Irradies, F-91191 Gif Sur Yvette, France
[2] CEA Saclay, CEA, DEN, Serv Corros & Comprtement Mat Leur Environm, F-91191 Gif Sur Yvette, France
[3] CEA, DEN, Serv Rech Met Appl, F-91191 Gif Sur Yvette, France
[4] Univ Versailles St Quentin, CNRS, UMR 8635, GEMaC, F-92195 Meudon, France
来源：
CORROSION SCIENCE | 2015年 / 98卷
关键词：
Zirconium; Reactor conditions; Hydrogen absorption; SIMS; TRANSMISSION ELECTRON-MICROSCOPY; PRESSURIZED-WATER REACTORS; SYNCHROTRON-RADIATION; OXIDE-FILMS; ZR ALLOYS; OXIDATION; TEMPERATURE; HYDROGEN; PRETRANSITION; TRANSPORT;
D O I：
10.1016/j.corsci.2015.05.058
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In Pressurized Water Reactors, zirconium hydrides precipitate in the matrix and could increase the oxidation rate of the claddings. To understand their effect, corrosion tests, TEM and mu-XRD analyses have been performed. This work showed that the oxidation rate and the oxygen diffusion coefficient in the oxide formed on massive hydride are much greater than those of Zircaloy-4. Moreover, oxide characterizations indicated an additional phase indexed as the sub-oxide Zr3O between the oxide film and the massive hydride. Finally, the hydrogen of the hydrides is not incorporated in the oxide during the corrosion process. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：478 / 493
页数：16
相关论文
共 50 条
  • [31] Corrosion of Chromium Coating Fabricated on Zircaloy-4 Substrate
    Golgovici, Florentina
    Diniasi, Diana
    Dinca, Paul Pavel
    Butoi, Bogdan
    Demetrescu, Ioana
    MATERIALS, 2024, 17 (18)
  • [32] Effect of surface nanocrystallization on the corrosion behavior of Zircaloy-4
    Zhu YuTao
    Zhang XiYan
    SCIENCE IN CHINA SERIES E-TECHNOLOGICAL SCIENCES, 2009, 52 (08): : 2227 - 2231
  • [33] Effect of surface nanocrystallization on the corrosion behavior of Zircaloy-4
    YuTao Zhu
    XiYan Zhang
    Science in China Series E: Technological Sciences, 2009, 52 : 2227 - 2231
  • [34] Effects of β phase quenching on the corrosion resistance of zircaloy-4
    Zhou, Bangxin
    Li, Qiang
    Miao, Zhi
    Hedongli Gongcheng/Nuclear Power Engineering, 2000, 21 (04): : 339 - 343
  • [35] Corrosion of zircaloy-4 in aqueous solutions of LiOH and KOH
    Liu, WQ
    Li, Q
    Zhou, BX
    Yao, MY
    RARE METAL MATERIALS AND ENGINEERING, 2004, 33 (07) : 728 - 730
  • [36] EFFECT OF NIOBIUM ADDITIONS ON CORROSION BEHAVIOR OF ZIRCALOY-4
    SABOL, GP
    MCDONALD, SG
    JOM-JOURNAL OF METALS, 1976, 28 (12): : A47 - A47
  • [37] The influence of solid solution hydrogen and precipitated hydride on the creep behavior of Zircaloy-4
    Kim, Ho -A
    Choi, Sungjun
    Kim, Yong-Soo
    Park, Jiwon
    Kang, Joo-Hee
    Kim, Sangtae
    JOURNAL OF NUCLEAR MATERIALS, 2024, 600
  • [38] Plasma electrolytic oxidation and corrosion protection of Zircaloy-4
    Cheng, Y.
    Matykina, E.
    Arrabal, R.
    Skeldon, P.
    Thompson, G. E.
    SURFACE & COATINGS TECHNOLOGY, 2012, 206 (14): : 3230 - 3239
  • [39] OXIDATION AND CORROSION OF TIN-COATED ZIRCALOY-4
    HAUFFE, K
    MARTINEZ, V
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (05) : 595 - 602
  • [40] Effect of surface nanocrystallization on the corrosion behavior of Zircaloy-4
    ZHU YuTao1
    2 National Engineering Research Center for Magnesium Alloys
    3 School of Physical Science and Engineering Technology
    Science in China(Series E:Technological Sciences), 2009, 52 (08) : 2227 - 2231
12345