Syntheses and crystal structures of [(t-Bu4Sb4)Fe(CO)4], [(t-Bu4Sb4)Mo(CO)5], and [(t-Bu3Sb4)Mo(η5-C5Me5)(CO)3]

被引：0

作者：

Breunig, HJ ^{[1
]}

Rösler, R ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Inst Anorgan & Phys Chem, Fb 02, D-28334 Bremen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 10期

关键词：

antimony; iron complex; molybdenum complex; X-ray diffraction;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

t-Bu4Sb4 reacts with Fe-2(CO)(9) to form [(t-Bu4Sb4)Fe(CO)(4)] (1). [(t-Bu4Sb4)Mo(CO)(5)] (2) is formed from (thf)Mo(CO)(5) and t-Bu4Sb4. [(t-Bu3Sb4)Mo(eta(5)-C5Me5)(CO)(3)] (3) is a product of the reaction of t-Bu4Sb4 with [(eta(5)-C5Me5)Mo(CO)(3)](2). The crystal structures of 1-3 are reported.

引用

页码：1619 / 1623

页数：5

共 50 条

[41] Syntheses of Ir4(CO)6(5-C5Me4H)2 and Ir7(3-CO)3(CO)12(5-C5Me5) from Pentametallic Molybdenum-Iridium Cluster Precursors
Fu, Junhong
Randles, Michael D.
Criddle, Alan L.
Moxey, Graeme J.
Schwich, Torsten
Stranger, Robert
Cifuentes, Marie P.
Humphrey, Mark G.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (15) : 2587 - 2591
[42] [(η5-C5Me5)2Mo2 (μ-I)4]+ [FeI 4]-.[ (η5-C5Me5)2Mo2I2 (μ-I) 2(μ-O)]
Gordon, John C.
Fanwick, Phillip E.
Poli, Rinaldo
Acta Crystallographica, Section C: Crystal Structure Communications, 1996, 52 (Pt 5): : 1098 - 1101
[43] Decamethylpentasilacycloheptyne • Mo2(CO)4(η5-C5H5)2 and cycloheptyne • Mo2(CO)4(η5-C5H5)2
Cervantes-Lee, F
Parkanyi, L
Kapoor, RN
Mayr, AJ
Pannell, KH
Pang, Y
Barton, TJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 562 (01) : 29 - 33
[44] METAL-METAL MULTIPLE BONDS .18. ADDITION-REACTIONS OF DIAZOALKANES WITH THE MO=MO TRIPLE BOND IN C5H52MO2(CO)4, C5H4ME2MO2(CO)4, C5ME52MO2(CO)4
CURTIS, MD
MESSERLE, L
DERRICO, JJ
BUTLER, WM
HAY, MS
ORGANOMETALLICS, 1986, 5 (11) : 2283 - 2294
[45] CRYSTAL STRUCTURES OF PENTAETHYLCYCLOPENTAPHOSPHINEMOLYBDENUM TETRACARBONYL (ETP)5MO(CO)4 AND TETRAETHYLCYCLOTETRAPHOSPHINETUNGSTEN TETRACARBONYL (ETP)4W(CO)4
BUSH, MA
COOK, VR
WOODWARD, P
CHEMICAL COMMUNICATIONS, 1967, (13) : 630 - &
[46] THE ADDITION OF HALOGENOCARBONS TO ALKENES IN THE PRESENCE OF [MO2(CO)4(ETA-C5H5)2], [MO2(CO)4(ETA-C5ME5)], [MO2(CO)6(ETA-C5H5)2] AND [(MO(CO)3(ETA-C5H4))2CH2]
DAVIS, R
KHAZAL, NMS
BITTERWOLF, TE
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 397 (01) : 51 - 58
[47] Synthesis and photolysis of [M(CO)3H]2(η5,η5-C5H4CH2C5H4), where M = Mo and W.: Photochemical 'twist' rearrangement of M2(CO)6 (η5,η5-C5H4CH2C5H4) to give [M(CO)3][M(CO)3H](η5,η5:η1-C5H4CH2C5H3), where M = Mo and W.: The molecular structure [Mo(CO)3][Mo(CO)3Cl](η5,η5:η1-C5H4CH2C5H3)
Bitterwolf, TE
Saygh, A
Haener, JL
Fierro, R
Shade, JE
Rheingold, AL
Liable-Sands, L
Alt, HG
INORGANICA CHIMICA ACTA, 2002, 334 : 54 - 58
[48] INSERTION REACTIONS OF T-BU(ETA-5-C5H5)FE(CO)2
PANNELL, KH
GIASOLLI, T
KAPOOR, RN
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 316 (03) : 315 - 318
[49] Crystal growth and characterization of co-doped Ce2Fe4Sb5
Chan, Julia
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
[50] Novel Antimony Complexes: [Ph4Sb]4+[Sb4I16]4− · 2Me2C=O and [Ph4Sb]3+[Sb5I18]3−
V. V. Sharutin
A. P. Pakusina
O. K. Sharutina
O. A. Kovaleva
A. V. Gerasimenko
M. A. Pushilin
Russian Journal of Coordination Chemistry, 2004, 30 : 541 - 549

← 1 2 3 4 5 →