Syntheses and crystal structures of [(t-Bu4Sb4)Fe(CO)4], [(t-Bu4Sb4)Mo(CO)5], and [(t-Bu3Sb4)Mo(η5-C5Me5)(CO)3]

被引:0
|
作者
Breunig, HJ [1 ]
Rösler, R [1 ]
Lork, E [1 ]
机构
[1] Univ Bremen, Inst Anorgan & Phys Chem, Fb 02, D-28334 Bremen, Germany
来源
关键词
antimony; iron complex; molybdenum complex; X-ray diffraction;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
t-Bu4Sb4 reacts with Fe-2(CO)(9) to form [(t-Bu4Sb4)Fe(CO)(4)] (1). [(t-Bu4Sb4)Mo(CO)(5)] (2) is formed from (thf)Mo(CO)(5) and t-Bu4Sb4. [(t-Bu3Sb4)Mo(eta(5)-C5Me5)(CO)(3)] (3) is a product of the reaction of t-Bu4Sb4 with [(eta(5)-C5Me5)Mo(CO)(3)](2). The crystal structures of 1-3 are reported.
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页码:1619 / 1623
页数:5
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