A new route to tris(pyrazolyl)borate ligands and new structural variations in TlTp complexes

被引：48

作者：

Janiak, C

Braun, L

Girgsdies, F

机构：

[1] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

[2] Tech Univ Berlin, Inst Anorgan & Analyt Chem, D-10623 Berlin, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a902264c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(pyrazolyl)borate ligands were synthesized by a new route from MeBBr(2) and pyrazole derivatives under very mild conditions at room temperature to give TlL complexes. For L = [MeB(3,5-Me(2)pz)(3)](-) a bridging co-ordination of the ligand is found, interpreted as sterically enforced upon comparison with the structures for L = [MeB(3-Mepz)(3)](-) and [HB(3,5-Me(2)pz)(3)](-).

引用

页码：3133 / 3136

页数：4

共 50 条

[31] Photochemistry of tris(pyrazolyl)borate titanium(IV) complexes
Gazzi, R
Perazzolo, F
Sostero, S
Ferrari, A
Traverso, O
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (08) : 2071 - 2077
[32] BORATROPIC REARRANGEMENTS IN TRIS(PYRAZOLYL)BORATE MOLYBDENUM MONONITROSYL COMPLEXES - EFFECTS OF CO-LIGANDS
CANO, M
HERAS, JV
MONGE, A
PINILLA, E
SANTAMARIA, E
HINTON, HA
JONES, CJ
MCCLEVERTY, JA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (13): : 2281 - 2288
[33] Deep-blue emitting cerium(III) complexes with tris(pyrazolyl)borate and triflate ligands
Yan, Wenchao
Cai, Zelun
Qi, Hao
Guo, Ruoyao
Liu, Zhiwei
Bian, Zuqiang
DALTON TRANSACTIONS, 2022, 51 (08) : 3234 - 3240
[34] Tantalum Complexes Incorporating Tris(pyrazolyl)Borate Ligands: Syntheses, Structures, and Ethylene Polymerization Behavior
Michiue, Kenji
Oshiki, Toshiyuki
Takai, Kazuhiko
Mitani, Makoto
Fujita, Terunori
ORGANOMETALLICS, 2009, 28 (22) : 6450 - 6457
[35] Sterically bulky tris(triazolyl)borate ligands as water-soluble analogues of tris(pyrazolyl)borate
Jernigan, Finith E., III
Sieracki, Nathan A.
Taylor, Michael T.
Jenkins, Aaron S.
Engel, Sharon E.
Rowe, Brittany W.
Jove, Fernando A.
Yap, Glenn P. A.
Papish, Elizabeth T.
Ferrence, Gregory M.
INORGANIC CHEMISTRY, 2007, 46 (02) : 360 - 362
[36] Sterically bulky tris(triazolyl)borate ligands as water-soluble analogs of tris(pyrazolyl)borate
Jernigan, Finith E., III
Sieracki, Nathan A.
Taylor, Michael T.
Jenkins, Aaron S.
Engel, Sharon E.
Rowe, Brittany W.
Jove, Fernando A.
Yap, Glenn P. A.
Papish, Elizabeth T.
Ferrence, Gregory M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 728 - 728
[37] Bitopic bis- and tris(1-pyrazolyl)borate ligands: Syntheses and structural characterization
Bieller, S
Zhang, F
Bolte, M
Bats, JW
Lerner, HW
Wagner, M
ORGANOMETALLICS, 2004, 23 (09) : 2107 - 2113
[38] Copper(II) complexes of new potentially hexadentate N3S3- or N6-donor podand ligands based on the tris(pyrazolyl)borate or tris(pyrazolyl)methane core
Humphrey, ER
Mann, KLV
Reeves, ZR
Behrendt, A
Jeffery, JC
Maher, JP
McCleverty, JA
Ward, MD
NEW JOURNAL OF CHEMISTRY, 1999, 23 (04) : 417 - 423
[39] Combination of single-molecule magnet behaviour and luminescence properties in a new series of lanthanide complexes with tris(pyrazolyl)borate and oligo(β-diketonate) ligands
Mikhalyova, Elena A.
Zeller, Matthias
Jasinski, Jerry P.
Butcher, Raymond J.
Carrella, Luca M.
Sedykh, Alexander E.
Gavrilenko, Konstantin S.
Smola, Sergey S.
Frasso, Michael
Cazorla, Sebastian Calderon
Perera, Kuluni
Shi, Anni
Ranjbar, Habib G.
Smith, Casey
Deac, Alexandru
Liu, Youlin
McGee, Sean M.
Dotsenko, Vladimir P.
Kumke, Michael U.
Mueller-Buschbaum, Klaus
Rentschler, Eva
Addison, Anthony W.
Pavlishchuk, Vitaly V.
DALTON TRANSACTIONS, 2020, 49 (23) : 7774 - 7789
[40] Tris(pyrazolyl)borate amidoborane complexes of the group 4 metals
Fuller, Anna-Marie
Hughes, David L.
Lancaster, Simon J.
DALTON TRANSACTIONS, 2011, 40 (28) : 7434 - 7441

← 1 2 3 4 5 →