The Construction of a 3D Pr(III) Coordination Polymer Based on 2-Methyl Imidazole-4,5-dicarboxylate and Oxalate Ligands

被引：4

作者：

Chen, Nan ^{[1
]}

Wang, Chengjie ^{[1
]}

Guo, Mengwei ^{[1
]}

Gao, Yongchao ^{[1
]}

Li, Gang ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 07期

基金：

中国国家自然科学基金;

关键词：

crystal structure; imidazole dicarboxylate; polymer Pr(III); properties; LANTHANIDE-ORGANIC FRAMEWORK; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; HELICAL CHAINS; COMPLEXES; LUMINESCENCE; CONTRACTION; SERIES; ACID;

D O I：

10.1080/15533174.2012.680132

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvothermal reaction of Pr(NO3)(3)center dot 6H(2)O with 2-methyl-1H-imidazole- 4,5-dicarboxylic acid (H3MIDC) and ammonium oxalate affords a metal-organic framework, {[Pr-2(mu(3)-HMIDC)(2)(mu(2)-C2O4)(H2O)(3)]center dot EtOH center dot 3H(2)O}(n) (1), which has been structurally characterized by single-crystal X-ray diffraction. Polymer 1 exhibits a novel 3D structure, in which infinite 1D chains, composed of nine-coordinated Pr(III) ions and oxalates, were linked by mu(3)-HMIDC2- to give rise to a 3D architecture. Its thermal and solid-state fluorescence properties have been investigated.

引用

页码：981 / 986

页数：6

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