Electrocatalytic reduction of hydrogen peroxide at platinum microparticles dispersed in a poly(o-phenylenediamine) film

被引:51
|
作者
Cai, LT [1 ]
Chen, HY [1 ]
机构
[1] Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
poly(o-phenylenediamine); platinum microparticles; electrocatalysis; hydrogen peroxide; modified electrode;
D O I
10.1016/S0925-4005(99)00024-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The poly(o-phenylenediamine) (PoPD) film modified with highly dispersed platinum microparticles causes a great increase in electroactivity and the electrocatalytic reduction for hydrogen peroxide. The different metal-polymer configuration will strongly affect the electrochemical behavior and electrocatalytic activity of the composite film. The dependences of catalytic response on the potential scan rate, the pH, and the concentration of species are studied in detail. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:14 / 18
页数:5
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