Synthesis, Crystal Structure and Characterization of Energetic Monovalent Copper Azide Complex: [Cu2(dmpz)(N3)2]n

被引：0

作者：

Fan Guang ^{[1
]}

Li Xiao-Bo ^{[1
]}

Ma Zhan-Ying ^{[1
]}

Deng Ling-Juan ^{[1
]}

Zhang Yin-Li ^{[1
]}

Guo Jin-Chan ^{[1
]}

机构：

[1] Xianyang Normal Univ, Coll Chem & Chem Engn, Xianyang 712000, Shaanxi, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 34卷 / 10期

基金：

中国国家自然科学基金;

关键词：

monovalent copper azide complex; crystal structure; energetic complex; hydrothermal synthesis; high-energy density materials; THERMAL-DECOMPOSITION; SENSITIVITY; DETONATION; INITIATION;

D O I：

10.14102/j.cnki.0254-5861.2011-0712

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel cuprous azide complex with the formula of [Cu-2(dmpz)(N-3)(2)](n) (1, dmpz: 2,6-dimethylpyrazine) has been synthesized through hydrothermal synthesis with the reducibility of H3PO3 and structurally characterized by single-crystal X-ray diffraction method. Single-crystal X-ray diffraction analysis reveals the title complex represents a three-dimensional network structure featuring.2D [CuN3](n) plane units bridged by bridging dmpz ligands to form a 3D network. Research results reveal that 1 has lower impact sensitivity and friction sensitivity, which may be expected to become insensitive energetic material and have potential applications. Crystal data: monoclinic, space group C2/c, a = 17.8599(15), b = 8.2889(5), c = 14.8076(14) angstrom, beta = 113.2580(10)degrees, V =2014.0(3) angstrom(3), Z= 8, S= 1.025, the final R= 0.0303, wR= 0.0825 for 1460 observed reflections with I> 2 sigma(I) and R= 0.0386, wR = 0.0870 for all reflections. In addition, elemental analysis, IR, and sensitivity characterization are presented.

引用

页码：1508 / 1512

页数：5

共 50 条

[21] Copper(I) nitrate complexes.: Synthesis and crystal structure of [Cu2(μ-DATU)2(DATU)4](NO3)2 (DATU=N,N′-diallylthiourea)
Filinchuk, YE
Oliinik, VV
Schollmeier, D
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1999, 25 (03) : 209 - 213
[22] Energetic cuprous azide complex: synthesis, crystal structure, and characterization
Guang, Fan
Yin-Li, Zhang
Jia-Juan, Sun
Min-Yan, Zheng
JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (21) : 3711 - 3717
[23] CRYSTAL STRUCTURE OF [CU(N3)2 (C5H5N) 2]
AGRELL, I
ACTA CHEMICA SCANDINAVICA, 1969, 23 (05): : 1667 - &
[24] CRYSTAL STRUCTURE OF COPPER (2) COPPER (I) COMPLEX CU2(SCN)3(NH3)3
GARAJ, J
ACTA CRYSTALLOGRAPHICA, 1966, S 21 : A141 - &
[25] Synthesis, characterization and crystal structure of tetranuclear copper(II) complex [Cu4(μ-Salophen)2(μ1,1-N3)2(N3)2] with alternating μ1,1-azido and phenoxo bridges
Khalaji, A. D.
Triki, S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (08) : 579 - 582
[26] Tetranuclear azido-bridged copper(II) complex [Cu4(μ-salpn)2(μ1,1-N3)2(N3)2-(H2O)2]: Synthesis, characterization and crystal structure
Khalaji, Aliakbar Dehno
Stoekh-Evans, Helen
POLYHEDRON, 2009, 28 (17) : 3769 - 3773
[27] Synthesis, characterization and crystal structure of tetranuclear copper(II) complex [Cu4(μ-Salophen)2(μ1,1-N3)2(N3)2] with alternating μ1,1-azido and phenoxo bridges
A. D. Khalaji
S. Triki
Russian Journal of Coordination Chemistry, 2012, 38 : 579 - 582
[28] SYNTHESIS AND CRYSTAL-STRUCTURE OF THE AZIDO DINUCLEAR COPPER(II) CRYPTATES OF MACROCYCLIC LIGANDS [CU2(N3)2(C16H38N6)](CLO4)2
TONG, YZ
JIN, XL
XU, XJ
TANG, YQ
ACTA CHIMICA SINICA, 1991, 49 (01) : 48 - 52
[29] Synthesis and Crystal Structure of a Spiral-chain Manganese（Ⅲ） Complex Containing Azide Bridge,[Mn（bzan）N3]n
FENG Yun-Long (Institute of Physical Chemistry
结构化学, 2002, (04) : 352 - 354
[30] Crystal structure and EPR spectrum of dimeric di-μ-azide-bis[cyanide(N,N-diethylethylenediamine)]-copper(II), [Cu(N3)(NCO)(diEten)]2
O. E. Piro
E. E. Castellano
J. Zukerman-Schpector
C. A. De Simone
D. M. Martino
C. A. Steren
Journal of Chemical Crystallography, 1997, 27 : 129 - 135

← 1 2 3 4 5 →